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Frank Kasper phases : ウィキペディア英語版 | Frank Kasper phases
Frank-Kasper (FK) phases or topologically close-packed phases are one of the largest groups of intermetallic compounds, known for their complex crystallographic structure and physical properties. Owing to their combination of periodic and aperiodic structure, FK phases belong to the class of quasicrystals. Applications of FK phases as high-temperature structural and superconducting materials have been highlighted; however, they have not yet been sufficiently investigated for details of their physical properties. Also, their complex and often non-stoichiometric structure makes them good subjects for theoretical calculations. ==History== In 1958, Frank and Kasper, in their original work investigating many complex alloy structures, showed that non-icosahedral environments form an open-end network which they called the major skeleton, and is now identified as the declination locus. They came up with the methodology to pack asymmetric icosahedra into crystals using other polyhedra with larger coordination number and atoms. These coordination polyhedra were constructed to maintain topological close packing (TCP).
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